Significant others: Married to Brad Pitt with three adopted children, Maddox, Pax, and Zahara, and one biological child, Shiloh.

One minute rundown: "I am still at heart-and always will be-just a punk kid with tattoos", she said, after a history of moshing with a live-in boyfriend, living above a garage and cutting herself to ease the pain of being bullied throughout high-school. This multi-millionairess has definitely had the last laugh over all who mocked those distinctive features, however. Not only has the womb-raider stolen the hottest man in Hollywood from the fair hands of our fave Friends star Jennifer Aniston, the Jolie-Pitts are probably the most successful human beings on the planet...well, in the shallow pool that is celeb-ville, anyway.

Her first film role was the cult classic Hackers, where she met her first hubby, Jonny Lee Miller, and after a host of random roles she got lucky with her parts in Girl Interrupted, Tomb Raider and Gone In 60 Seconds. After a three year marriage with Billy Bob Thornton and freaking the world out by wearing his blood in a necklace, she admitted to swinging both ways, although sorted herself out when the Pittster entered stage-left in 2005. She currently lives a "thin" existence... all over the place, trotting the globe as a do-gooder Goodwill Ambassador and adopting half the third world's orphans as her own. Poor Brad - he must have the patience of a saint.